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91.
Using first principles calculations, we study fundamental mechanism of spontaneous reduction reaction of Eu3+ to Eu2+ in eutectic LiCl‐KCl molten salt. We decouple the reaction Gibbs free energy into enthalpy and entropy contributions by using rigorous thermodynamic formalism. Key structural features of the solvation shell are characterized by the radial distribution function and the coordination number. Compared with Eu2+, the Eu3+ ion has a more rigid framework of the solvation shells, corroborating its stronger electrostatic interaction with neighboring ligands of Cl? ions and a more favorable state on the aspect of enthalpy. Computations on vibrational frequency, however, pose significant contribution of vibrational entropy to the reaction Gibbs free energy for the reduction. Vibration frequency of Eu2+ is smaller than that of Eu3+, driving a more positive change of the entropy in the reduction reaction. Furthermore, an Eu2+ diffuses more quickly than an Eu3+ in the LiCl‐KCl molten salt with switching mechanism of ligand Cl? ions in the solvation shell. Our results propose that the spontaneity of the reduction reaction is driven by the entropic contribution by overcoming the penalty of the reaction enthalpy.  相似文献   
92.
针对多目标绿色柔性作业车间调度问题(MGFJSP)的特点,提出从碳排放量、噪声和废弃物这3个指标来综合评定环境污染程度,建立了以最小化最大完成时间和环境污染程度为优化目标的MGFJSP模型,并提出了一种改进的人工蜂群算法来求解该模型。算法的具体改进包括:设计了一种三维向量的编码和对应解码方案,在跟随蜂搜索阶段引入一种有效的动态邻域搜索操作来提高算法的局部搜索能力,在侦查蜂阶段提出产生新食物源的策略用于增加种群的多样性。最后进行了实验研究与算法对比,以验证所建模型和所提算法的有效性。  相似文献   
93.
In the cases that the historical data of an uncertain event is not available, belief degree-based uncertainty theory is a useful tool to reflect such uncertainty. This study focuses on uncertain bi-objective supply chain network design problem with cost and environmental impacts under uncertainty. As such network may be designed for the first time in a geographical region, this problem is modelled by the concepts of belief degree-based uncertainty theory. This article is almost the first study on belief degree-based uncertain supply chain network design problem with environmental impacts. Two approaches such as expected value model and chance-constrained model are applied to convert the proposed uncertain problem to its crisp form. The obtained crisp forms are solved by some multi-objective optimization approaches of the literature such as TH, Niroomand, MMNV. A deep computational study with several test problems are performed to study the performance of the crisp models and the solution approaches. According to the results, the obtained crisp formulations are highly sensitive to the changes in the value of the cost parameters. On the other hand, Niroomand and MMNV solution approaches perform better than other solution approaches from the solution quality point of view.  相似文献   
94.
以ACME台架的蒸汽发生器(SG)为研究对象,SG二次侧选用两流体模型,采用计算流体力学软件CFX对ACME台架的SG进行了整体直接模拟。针对稳定试验工况进行了计算,得到了SG一、二次侧的温度分布,二次侧空泡份额分布及传热管的壁温等参数沿U型管高度方向的变化,获得了二次侧较详细的流动和传热特性。计算结果表明,从第2道折流板开始,折流板底部已积聚了部分气泡,随高度的增加,折流板底部积聚的气泡越多,在弯管区附近及以上区域,已全部变为蒸汽。本文计算结果与试验结果符合较好。  相似文献   
95.
A macroscopic numerical method is proposed to study the flow distribution uniformity of a novel porous copper fiber sintered felt (PCFSF), which has gradient porosities and was developed as the methanol steam reforming micro-reactor catalyst support for hydrogen production for fuel cell applications. The macroscopic porous media developed by the ANSYS/FLUENT software is used to represent the PCFSF. Our results indicate that the gradient porosity can reshape the flow distribution of PCFSFs greatly, thus producing significant influence on their performance. It is further revealed that, for a PCFSF with a determined gradient porosity configuration but different reactant feed directions, the velocity uniformity can be used as a quantitative criterion to evaluate the performance of hydrogen production. Furthermore, new gradient PCFSFs are produced according to the flow distribution of original gradient PCFSFs. The preliminary experimental results of the new gradient PCFSFs of 0.8-0.9-0.7 and 0.7-0.9-0.8 exhibit better methanol conversion and H2 flow rate. This indicates that the numerical method can be used for the optimization of PCFSFs' gradient porosity configuration, which consists of the shape and position of the interfaces between different porosity portions, the number of interfaces and the porosity distribution in different portions.  相似文献   
96.
水下循迹航行器水动力学性能数值研究   总被引:2,自引:0,他引:2  
为了研究低速水下循迹监测航行器的水动力学性能数值计算问题,采用FLUENT软件和SST剪切应力输运模型,通过雷诺时均N-S方程分析流速一定的情况下,取不同攻角、不同水平舵角作为来流条件,研究未安装推进器以及安装推进器且其安装位置不同时,航行器的升力系数、俯仰力矩系数、表面压力分布和流场速度的变化规律。结果表明:在未安装推进器以及推进器的安装位置不同时,随着攻角的变化,升力系数呈线性变化,俯仰力矩系数呈非线性变化;随着水平舵角的变化,升力系数和俯仰力矩系数呈线性变化。当推进器安装在航行器头部时,对航行器流场压力和流场速度变化影响最大;当安装在航行器尾部时,对二者影响最小。对于低速航行器,应尽量将推进器安装在中间靠后位置,以提高航行器的水动力性能。升力系数的试验结果与数值仿真结果之间最大相差7. 51%,阻力系数的试验结果与数值仿真结果最大相差5. 84%,均吻合较好。研究结果可以为低速水下循迹航行器的优化设计和发展提供理论参考。  相似文献   
97.
Three classes (normal, PSE‐like and woody, thirty for per class) of fresh chicken breast meats were selected from a Chinese processing plant. Then, three classes of chicken breast meats were used to prepare meat batters and meatballs. This study investigated the effects of three classes of chicken breast meat on the physicochemical properties, water distribution, protein secondary structures and microstructures of meatballs. PSE‐like and woody meatballs both had lower water holding capacity and textural properties than normal meatballs. Furthermore, the free water mobility and proportion in PSE‐like and woody meatballs were increased (< 0.05). According to near‐infrared spectroscopy results, the intensity of the 1940‐nm bands of PSE‐like and woody classes both increased. Both PSE‐like and woody meatballs formed more aggregated gel matrices than normal class. PSE‐like and woody classes had higher α‐helix and lower β‐structure contents (< 0.05). Overall, compared with normal meatballs, PSE‐like and woody meatballs showed inferior functional properties.  相似文献   
98.
针对5G基站设备相对于以往2G/3G/4G设备的变化,面向一线勘察设计人员,阐述5G基站在供配电需求方面功耗增大、供电方式多样化、供配电改造工作量和难度加大等相应变化,归纳相应的勘察前期准备工作要点,分析在实际工作中可能面临的外市电引入改造、供电方式选择的多样性、新型锂电池应用等重点、难点,介绍理想的5G供配电模式及发展方向,最后提出5G基站供配电勘察设计工作思路调整的建议。  相似文献   
99.
在介绍国内外输电线路现有机器人研究基础上,针对配电线路绝缘修复领域短板,开发了一套能够在线修复配电线路绝缘皮损伤的包裹机器人。首先,对绝缘包裹机器人的机械结构进行了设计研究,包括行走装置、升降装置和柔性输送与包裹装置;然后,开发了相应的控制系统,包括无线通讯、视觉系统等,并对其进行了抗干扰试验和耐压试验,试验结果合格;最后,通过现场绝缘包裹测试完成了机器人的功能性与可靠性验证。本项目所研发的机器人突破了在线修复、柔性包裹等技术瓶颈,解决了人工修复带来的一系列问题。样机通过现场带电包裹试验,绝缘包裹效果符合行业标准要求,达到了预期效果。  相似文献   
100.
Electromagnetic hyperthermia as a potent adjuvant for conventional cancer therapies can be considered valuable in modern oncology, as its task is to thermally destroy cancer cells exposed to high-frequency electromagnetic fields. Hyperthermia treatment planning based on computer in silico simulations has the potential to improve the localized heating of breast tissues through the use of the phased-array dipole applicators. Herein, we intended to improve our understanding of temperature estimation in an anatomically accurate female breast phantom embedded with a tumor, particularly when it is exposed to an eight-element dipole antenna matrix surrounding the breast tissues. The Maxwell equations coupled with the modified Pennes’ bioheat equation was solved in the modelled breast tissues using the finite-difference time-domain (FDTD) engine. The microwave (MW) applicators around the object were modelled with shortened half-wavelength dipole antennas operating at the same 1 GHz frequency, but with different input power and phases for the dipole sources. The total input power of an eight-dipole antenna matrix was set at 8 W so that the temperature in the breast tumor did not exceed 42 °C. Finding the optimal setting for each dipole antenna from the matrix was our primary objective. Such a procedure should form the basis of any successful hyperthermia treatment planning. We applied the algorithm of multi for multi-objective optimization for the power and phases for the dipole sources in terms of maximizing the specific absorption rate (SAR) parameter inside the breast tumor while minimizing this parameter in the healthy tissues. Electro-thermal simulations were performed for tumors of different radii to confirm the reliable operation of the given optimization procedure. In the next step, thermal profiles for tumors of various sizes were calculated for the optimal parameters of dipole sources. The computed results showed that larger tumors heated better than smaller tumors; however, the procedure worked well regardless of the tumor size. This verifies the effectiveness of the applied optimization method, regardless of the various stages of breast tumor development.  相似文献   
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